Air vents do not work without actual positive pressure in fact when there is negative pressure they will actually allow air into your system, remove them. if you do not have any check valves in your system or circ checks then the best way I know of to eliminate air from the start is by using your domestic water pressure to push the air back to the boiler tank and out the vent.by opening the supply and closing the return then using the domestic water pressure, all the air gets pushed back to the boiler, now close the supply and open the return to push it clean, close the domestic, open both valves on the supply and return, turn on the circ and enjoy the heat