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Always place the heat exchanger before the HWH. If not you will get fluctuation in water temperature. The water temp coming from the heat exchanger depends on two things, boiler temps and water flow. In other words if you have the heat exchanger in line after the HWH you run the risk of having the temps change if more than one faucet is on at a time. For example, lets say you are taking a shower and the dishwasher kicks on. Because there is higher water flow going through the heat exchanger the water temp drops a little. The water becomes a little cool for you and you add more hot. Now the dishwasher stops. Now the water is too hot so you adjust it cooler. Then your wife turns of the sink and your shower cools again. Get the picture? By placing the heat exchanger before the HWH you will allow the HWH to become a storage tank of consistent hot water. When the water from the heat exchanger fluctuates it then mixes with the 50 gal in the HWH and little fluctuations are never felt.
My point is that if you install it before the HWH you will most likely never use a mixing valve, the HWH does the work for you. Adjust your furnace temp to what domestic water temps work well for you and you are good to go. I never have understood and benefit to installing the heat exchanger past the HWH. I have installed hundreds of furnaces for years and have never used mixing valves for domestic hot water and have never had any problems.