First question, is your OWB closed loop or open??
Reason I ask is that, open loop systems generally do not require an air scoop
...on second look I am guessing system in closed loop due to the addition of heat dump (slant fins in shed)
#3 It may be a better idea to have a single pump on each line feeding a building; reason being you can't garentee flow, with 1 pump, especially if load (head pressure) in unbalance ***but since house is not running right now it should be OK of this year***
#4 Four-way mix valve should work, I have never worked with one before but have seen many 3-way valves. If you would have stated 3-way mix I would have recommended setting up the mix portion as a secondary loop of the primary loop from boiler, for less flow restrictions
About pumps, it is best practice to pump away from the boiler (an entire book was written on the subject).
***WHEN FILLING AND PURGING SYSTEM, REMEMBER ITS EASIER TO LET AIR RISE UP THAN TO FORCE IT DOWN***