if we assume your thermopex is 1 inch and you say 65 feet one way so we double that to 130 and add a few feet for fittings and such and we say your total pipe is 150 feet ....now we estimate your gpm required floor heat in 1/2 inch pex is said to not exceed .6 gpm, you have 12 loops in 2 zones so you require 7.2 gpm and your baseboard would be (if a 3/4 single tube) likely need a minumum of 1 gpm so you need about 8 we can say 9 for safety.
you need to move 9 gpm at about 16 feet of head.....taco 0014 or equivilent at the owb
the 07 you have now is likley delivering about 5 gpm (that is around 50,000 btu per hour and that could be not quite enough on a cold night for a house of your size)
get that delivery up to 9 or 10 gpm and you will be delivering enough, your floor loops should be able to extract about 75,000 (or more) and your baseboard about 500 btu per foot of length of the baseboard.