The wife and I like a cool house when sleeping so we have our programmable set to drop to 67 at night, about an hour or so before we normally get up it's set to bring the temp back up to 71.
It all depends on your house as well, a very well insulated house with at least double pane windows shouldn't place a huge load on the boiler while an older house with wood single pane windows and little to no insulation may take a LONG time to bring back up a couple of degrees. Depends on how many hours your running at a lower temp as well, if your only running at a lower temp for a few hours it very well may take more wood to bring the temp back up than you save.
When I first installed my home built boiler setting the thermostat lower at night would guarantee it take half the day to get those 4-5 degrees back in the morning. But since then we've added a foot of insulation to the attics, blue board, house wrap, new siding and replaced the tired old single pane windows with vinyl double pane windows, is no problem to bring the temp up in the mornings now.