i'll try to explain why thermostatic valves are used in the first place..........
manufacturers know that only a few of there dealers truly size the install correctly as there is no formal training, most simply do this on the side. what dealers they do have that do a correct install, still cant predict what there customers may add to there sytem once they leave or years down the road. So with that being said, empyre and cb and maybe more require some form of boiler protection to protect the boiler from over load and potentially incorrect installs
For example, i show up, design a system to have proper flow and return temps, i leave and the customer decides i'm an idiot and adjusts his temps down to 160 instead of 180, at which i would have designed the install around. OR, perhaps i leave and the customer builds on an addition or adds a hot tub, when folks start adding things to exsisting loops it throws the calculations out of whack and can lead to return temps being to low and causing the firebox to sweat inside
now, where does the "sweat" come from? its inside the wood, if you throw in 100 pounds of wood with 30% moisture, thats 30 pounds of water. If you have a cold spot, some of that moisture can build up there and drip into the ashes.
in this situation it seems apparent that this customers water temp only drops below 150 when his fire is nearly out or burned down to a bed of coals, at that point there is no moisture left in the wood to possibly build up and cause it to sweat, i hope this clarifies what i meant