Thanks Sprinter - i understand the pv=mrt rule, but i'm not quite understanding what you're saying about my boiler. It's not pressurized so it should always be equal due to being open to atmosphere correct?
If you goto Calefi Idronics edition wood boilers they have diagrams of how you can achieve boiling under 212 degrees in an open system. I was referring to open systems, since we know increasing pressure raises the boiling point. Open systems are at risk of sub atmospheric conditions because they are not pressurized.
This is especially true when very large pumps are used, or when any part of the system is above the boiler water level. We understand siphoning right? Well when we pump water uphill it has to fall back down, thus creating a siphon or suction on the downhill side of loop. This suction creates all kinds of problems, sucking air in thru any air vents, valve packings, seals, etc. air can be the gurgling, or when the suction side goes sub atmospheric, ie. reduced pressure, you can get boiling in spots.
Another way is when a rediculously oversized circulator is used. Our pumps do not pump water at all, they circulate water by changing pressure on either side of the circulator. Water naturally wants to equalize, and this creates flow. Taco has a video showing this, and exactly how circulators work in hydronics. The circ itself can cause boiling, also all these OWB's usually have 1" ports, or let's say they have too small a port for the circ and pipe in the application. Well do we understand velocity stacks on carburetors, and the Bournoole principal. Shoving too much water too fast thru 1" pipe for instance creates positive pressure, now when it enters a large open volume of water there is a rapid change in pressure. Same for the supply side. Increasing circ speed would increase the issue and slowing it down by speed switch or valve would reduce the symptoms.
These are just some possibilities, you might have a hot spot, but that would have to be one very bad jacket design to do so. You would have to move much less than 4gpm through a 1" port to not disturb stratification layers in the boiler. If I had to bet, I'd look at other possibilities like mentioned above.
Just look up the threads I started with all the links to tons of hydronic info