I don't ever recommend building yourself. 1% of those who do succeed with a viable boiler. Copying an existing proven design is your first step to being a 1 per center. It really takes a skillful person, and unless you already have the right materials, it can get expensive fast. I would only think of doing it, if I had the materials for free. With the prices of used units or even a starter model in the ridge wood line, it's really hard to justify home built , from a cost or ROI point of view.
Besides all that, I think I would copy a garn type design. It's what most do, a barrel in a barrel, or box in box. If you can add the extra flue pipe inside the unit to extract more great. Copper coils are great, but 3/4" soft copper is over $600 for a 100' coil. And for good heat transfer 4gpm@40degree rise is about 65' long coiled up. Rough estimate, there's a calculator for this.
Good luck, but your time is worthy too