Check water temperature leaving the boiler and water temperature entering the house. Also check water temperature entering the water/water HX and water temperature exiting it too.
Your water/water HX is rated at 300,000 BTU and you've already stated that you can only get half of that amount with your maximum flow. It's also possible that you won't be able to achieve 15 GPM through 1" PEX. I don't remember the numbers on flow vs size, but 15 GPM seems high for 1" PEX. I'm sure someone will chime in on that.
Another possible cause is that you're heating your domestic water prior to heating your house and that might be sucking away too much heat from the wood boiler's water to leave you enough to heat your house. If it's not too difficult, I'd reverse the order and see what your system is capable of at that point. It looks like you used a good deal of shark bite fittings, so switching things around should be simple.
Also, verify that your water/water HX isn't plugged up with something like a chunk of plastic or anything else during installation.